I already wrote about why you should
shoot raw, and why you should calibrate your monitor (in
two parts even!). Lets put these things together.
I read so very often about how people struggle with their white balance settings, and there's articles on the internet
how to deal with it, and how some people prefer warmer colors anyway, etc. (a really helpful tutorial can be found
here). And I remember how I did struggle, too, when I still shot JPEG. Setting WB to "cloudy" to get warmer color, but then adjusting it just a little bit so that it won't get too warm, and whatnot. What - a - nuisance!
When you're shooting raw, you can safely leave the white balance control of your camera set to auto. White balance is not applied to the raw sensor data, anyway. Its just saved as a "suggestion" into the file, and the raw converter software of your choice can extract the white balance the camera suggested and apply it. You're completely free to alter it to whatever setting you want (within certain limits, its possible to adjust the white balance in Picasa, too, of course -
this nice blogpost shows you how).
The other observation is... when your monitor is calibrated, its quite surprising how often the auto white balance of the camera is right on, or at least very very close to what I saw. Which is not a miracle -
6500K is the white point of the camera, and its the calibrated white point of my monitor, two.
Photography can always be approached from two directions: a most accurate reproduction, or a most pleasing result (to you, at least). And shooting raw and using a calibrated displays makes sure you can have both without any hassle. And thats a good thing! :-)